A fuel cell is an electrochemical device that combines hydrogen with oxygen to generate electricity, heat and water to produce. In many ways, the fuel cell is similar to an electrochemical cell. Instead of a regular charge, a continuous supply of oxygen and hydrogen is supplied from outside. Oxygen is produced in the control of air and hydrogen as a fuel made from a pressure instrumentation container. Alternatively, methanol, propane, butane, natural gas supply and diesel are used. (more…)

Transport applications tend to demand rapid start-up and instant dynamic response from fuel cell systems, so a high-temperature fuel cell is unlikely to be competitive as the main engine in applications such as cars and buses. The prime candidate for these vehicle propulsion systems is the Polymer Electrolyte Fuel Cells, which exhibits both of the above characteristics while also having very high power density. This is important as it must also occupy a similar amount of space to an internal combustion engine. Of recent interest has been the development of auxiliary power units for vehicles, in which the fuel cell meets the onboard electric load of the vehicle. Both Polymer Electrolyte Fuel Cells and ITSOFCs are under development for this application. (more…)

Fuel cells are typically classified according to type of electrolyte. While many varieties of fuel cells have been demonstrated in the laboratory, five major types are seeing development for commercial applications:

* Polymer electrolyte membrane (PEM) cells use a plastic (polymer) membrane that becomes electrically conducting when hydrated (saturated with water); they operate near 1001C.
* Alkaline fuel cells use a caustic electrolyte such as potassium hydroxide (KOH); they also operate near 1001C. (more…)

Polymer Electrolyte Fuel Cells have high-power density, rapid startup, and low-temperature operation (around 80 to 120 C), and so are ideal for use in applications such as energy transport and battery replacement. The electrolyte used is a proton conducting polymer. This is typically a perfluorinated polymer, though other hydrocarbon-based membranes are under development in an attempt to reduce cost or to enable operation at temperatures approaching 200 C. The catalytically active layer sits adjacent to the membrane, supported on a PTFE treated carbon paper, which acts as current collector and gas diffusion layer. For operation on pure hydrogen, platinum is the most active catalyst, but alloys of platinum and ruthenium are used when higher levels of carbon monoxide are present (CO is a poison in all low temperature fuel cells). (more…)

The fuel cell can trace its roots back to the 1800s when a Welsh-born, Oxford-educated barrister, Sir William Robert Grove, realized that if electrolysis, using electricity, could split water into hydrogen and oxygen, then the opposite would also be true. Grove subsequently built a device that would combine hydrogen and oxygen to produce electricity—the world’s first gas battery, later renamed the fuel cell. (more…)