Photoelectrolysis Using Metal Oxides And Other Semiconductors

Photoelectrolysis
Certain materials, generally metal oxides, can sustain the unassisted photo-electrolysis of water into H2 and O2. The energy contained in the photons that are absorbed by these materials can in many cases be efficiently converted into energy stored into the chemical fuels produced by the photo-electrolysis system. However, these materials have optical absorption thresholds (band gaps) that are too large to permit effective absorption of the visible and infrared portions of the solar spectrum, thereby wasting a large fraction of the incident solar energy and yielding overall energy conversion efficiencies of o 1%. Modification of metal oxide materials has been claimed to be much more promising, with a modified TiO 2 photo-anode yielding 8% efficiency in the photo-assisted splitting of water into H2 and O2 . (more…)

Photo-Electrochemical Energy Conversion Device

The basic processes that occur in such a system are well understood. The semiconductor electrode efficiently absorbs light, producing an excited electronic state. In this excited state, the electron and the electron vacancy (the ‘‘hole’’) are both more energetic than they were in their respective ground states. The photo-excited electrons and holes are generally not tightly bound to an individual atom or set of atoms in the solid. (more…)

Artificial Photosynthetic Devices

Several molecular systems have been constructed that mimic various aspects of photosynthesis. Two of these utilize molecular systems that are derived from natural photosynthesis but that incorporate chemically based modifications to produce artificial photosynthetic devices. These devices use artificial photosynthetic pigments to drive chemical reactions across lipid bilayers or use noble metal catalysts to change the function of the photosynthetic process to produce hydrogen and oxygen instead of sugars ethanol and oxygen. Neither of these systems are sufficiently robust to be operated for extended periods of time as energy unit conversion devices, but they have shown that it is possible to produce artificial photosynthetic assemblies that function well in a laboratory setting. (more…)

Hydrogen Conversion Kit Gasoline – Hydrogen Fuel Conversion

hydrogen conversion kit gasolineHydrogen has many applications when it comes to fuel. It can be used both in internal combustion engines and hydrogen fuel cells. Hydrogen engines are using the same principle the same way as gasoline fuels or hydrogen natural gas burned combustion, while the chemical energy of hydrogen used to generate electricity and heat transmission. Since the electrochemical reactions produced more efficient energy compare to the combustion energy, fuel cells are created more efficient fuel compare to internal combustion engines. In the long term it will benefit to the more efficient hydrogen conversion process. (more…)