The basic processes that occur in such a system are well understood. The semiconductor electrode efficiently absorbs light, producing an excited electronic state. In this excited state, the electron and the electron vacancy (the ‘‘hole’’) are both more energetic than they were in their respective ground states. The photo-excited electrons and holes are generally not tightly bound to an individual atom or set of atoms in the solid. (more…)

Different lasers use different materials as the active medium. The medium can be either solid, liquid, or gas, and there are advantages for each in the amount of energy that can be stored, ease of handling and storage, secondary safety hazards, cooling properties, and physical characteristics of the laser output. (more…)

The idea of using an absorption fluid as a refrigerant carrier derived from the drawback of VCR (vapor–compression refrigeration) systems that the gas compression requires a high work input. A pump that requires practically no work to increase the pressure in the refrigeration system replaces the complicated and work-consuming compressor. There are two major advantages of absorption refrigeration systems (ARSs) compared with VCRs (vapor–compression refrigeration): No CFCs or HCFCs are used as refrigerants, and they use heat from different sources, such as combustion, industrial processes, waste heat (an economical solution for recovery), or solar heat. (more…)

Geothermal wells need to undergo a test program before they are used. This is so that the baseline conditions of both the wells and the geothermal aquifers that they tap can be determined. This baseline data are critical because all future information is compared against them.

After drilling has been completed and before the initial discharge, the well downhole conditions are measured. The temperature and pressure are measured by using a clockwork Kuster gauge or electronic logging tools. Standard practice is to initially do an injection (or completion) test, that is, sometime at a series of flows, where the temperature, pressure, and possibly flows using a spinner tool are measured at intervals down the open hole section of the well. (more…)

With ethanol’s future uncertain, many commentators see the transportation debate evolving into a war between two other technologies—hydrogen-powered fuel cells and battery powered electric vehicles. Some alternative fuel advocates are putting their support behind hydrogen, the most abundant element on Earth. Water, for example, is composed of hydrogen and oxygen molecules. Hydrogen can be produced from water by electrolysis, which separates the oxygen from the hydrogen. It can be used to power hydrogen fuel cells for vehicles (or to provide heat and electricity for buildings). Hydrogen fuel cells work by recombining hydrogen and oxygen—a process that produces electricity, heat, and water. Hydrogen-powered cars, therefore, could be an ideal transportation solution—nonpolluting, zero-emission vehicles that release only water, a natural and completely safe waste product. Also, fuel cells are highly efficient and powerful, and unlike typical batteries, fuel cells will never lose their charge as long as hydrogen fuel is supplied.

Hydrogen fuel cell technologies, however, must overcome many stubborn challenges before they can become a practical source of energy. Perhaps the biggest obstacle is cost; it currently takes more energy to make hydrogen than is produced, and production relies on expensive catalysts made from platinum, a scarce metal. And like biofuels, hydrogen is currently made using fossil fuels, so it is not emissions-free. In addition, liquid hydrogen fuel is highly flammable and must be stored at very low temperatures or under very high pressure, making transport and storage difficult. Switching vehicles to hydrogen fuel cell power also would require building a whole new infrastructure similar to the chain of gas stations that currently dot the landscape. Researchers are hoping to find answers to these problems by searching for other types of catalysts, studying other ways to improve production, and developing better hydrogen storage options.

Hydrogen researchers, however, have been promising breakthroughs since the 1990s with little progress to show for their efforts. Many observers are thus coming to the conclusion that the hydrogen fuel cell is a technology that will not be perfected in the near future. As physicist and climate expert Joe Romm explains, “Neither government policy nor business investment should be based on the assumption that these technologies will have a significant impact in the near or medium-term.” The Obama administration apparently agrees; it submitted a budget for 2010 that sharply cut back on government support for hydrogen projects. U.S. Energy Secretary Steven Chu explained the administration’s problems with hydrogen technology:

Right now, the way we get hydrogen primarily is from reforming [natural] gas. That’s not an ideal source of hydrogen. . . . The other problem is, if it’s for transportation, we don’t have a good storage mechanism yet. Compressed hydrogen is the best mechanism [but it requires] a large volume. We haven’t figured out how to store it with high density. What else? The fuel cells aren’t there yet, and the distribution infrastructure isn’t there yet. So . . . to get significant deployment, you need four significant technological breakthroughs. That makes it unlikely

Congress promptly reversed President Obama’s decision, however, restoring more than $200 million to 190 hydrogen projects around the country.

The total installed geothermal power generating capacity in the world is approximately 9000 MWe from 21 countries, with the United States leading at nearly 3000 MWe and The Philippines with nearly 2000 MWe (Table II). Other major countries are Italy, Mexico, Indonesia, Japan, and New Zealand, with between 400 and 800 MWe each. (more…)

The moisture content of the feedstock affects the gas composition and the energy balance of the process since gasification is an endothermic process. Water vapor, however, is an essential component of gasification reactions. Therefore, there is a trade-off between the extent of fuel drying and the quality of product gas. Drying of the feedstock to a moisture content of approximately 15% is commonly adopted. Fuel drying is likely to be the most energy intensive activity in the biomass gasification process. Important contributions can be made to the energy balance by using flue gases or steam to dry the biomass. The heat used for drying does not have to be high temperature, and a low temperature level is actually desired because it will prevent the evaporation of undesirable organic components. (more…)

Microtechnology-Based Energy and Chemical Systems will most likely employ combustion for driving processes such as vapor generation and vapor barrier, endothermic chemical reactions, and (most notably) fuel reforming. Both fuel reformers and combustors will be of a miniature design relying on embedded catalysts for promoting chemical reactions at moderate temperatures (350–7501C). Many potential configurations exist depending on the application and constraints on the design. Microchannel arrays are a potential configuration; mesh and post architecture is another to achieve the desired surface area and small diffusional lengths necessary. (more…)

Gasification is a thermo chemical process that has been exploited for more than a century for converting solid feedstocks to gaseous energy carriers. The first gasifier patent was issued in England at the end of the 18th century and producer gas from coal gasification was mainly used as lighting fuel throughout the 19th century. At the turn of the 20th century, the main use of producer gas, obtained essentially from coal, switched to electricity generation and automotive applications via internal combustion engines. The use of producer gas was gradually supplanted by the use of higher energy density liquid fuels and as a result confined to areas with expensive or unreliable supplies of petroleum fuels. (more…)

At present, in the United States and worldwide, motor vehicles are fueled almost exclusively by petroleum based gasoline (or reformulated gasoline) and diesel fuels. Since the first oil price shock in 1973, efforts have been made to seek alternative fuels to displace gasoline and diesel fuels and achieve energy and environmental benefits. Some of the alternative fuels that have been researched and used are liquefied petroleum gas (LPG), compressed natural gas (CNG), liquefied natural gas (LNG), methanol (MeOH), dimethyl ether (DME), Fischer– Tropsch diesel (FTD), hydrogen (H 2 ), ethanol (EtOH), biodiesel, and electricity. Production processes associated with gasoline, diesel, and each of these alternative fuels differ. (more…)