Earth’s climate is a complex system of interacting natural components. These components include the atmosphere, the ocean, and the continental ice sheets. Living things on earth—or, the biosphere—also constitute an important component of the climate trends system.

Numerous factors influence Earth’s climate system, some of them natural. For example, the slow drift of continents that takes place over millions of years, a process known as plate tectonics, influences the composition of the atmosphere through its impact on volcanic activity and surface erosion. (more…)

Addressing global warming, however, is a highly complex and daunting endeavor. Many climate experts have urged the world to stabilize greenhouse gas concentrations in the atmosphere around 450 to 550 parts per million (ppm)—that is, no more than 450 to 550 units of greenhouse gases for every million units of air in the earth’s atmosphere. This approach, experts say, could keep average global temperatures at no more than 3.6° Fahrenheit (2° Celsius) above preindustrial levels, which could avoid some of the worst, irreversible consequences of climate change. (more…)

The product gas can be burned in boilers to generate heat and raise steam, in internal combustion engines to generate electricity and heat at small to medium scale (from a few kilowatts to a few megawatts), and in gas turbines to generate electricity (Brayton cycle) and heat at small to large scale. In large-scale systems using gas turbines, the exhaust gas from the gas turbine can be used to raise steam in a heat recovery steam generator to generate additional electricity using a steam turbine (Rankine cycle), resulting in combined cycle operation. (more…)

Biomass Storage

Biomass storage is required to ensure the continuous operation of the facility. To limit the space required for storage at the plant site, biomass must be stored in relatively high piles. Two main problems associated with fuel storage are decomposition and selfheating. Self-heating increases the rate of decomposition and fire risk, and it encourages the growth of thermophilic fungi whose spores can cause a respiratory condition in humans similar to farmers lung. Some small virgin biomass losses may occur at the storage stage, but they are likely to be negligible. For intermediary storage of the fuel between the pretreatment (e.g., drying and sizing) and gasification stage, storage silos may be used. (more…)

Options for dealing with the threats of climate change include both adaptation to inevitable changes and mitigation, or lessening, of those changes that we can still affect. One possible adaptation would be to adjust our agricultural practices to the changing regional patterns of temperature and rainfall. Another would be to build coastal defenses against the inundation from sea-level rise. Only mitigation, however, can prevent the most threatening changes. (more…)

Still hotly debated by some, human-induced global warming is now accepted in the scientific community. Earth’s average yearly temperature is getting steadily warmer; sea levels are rising due to melting ice caps; and the resulting impact on ocean life, wildlife, and human life is already evident. The human-induced buildup of greenhouse gases in the atmosphere poses serious and diverse threats to life on earth. As scientists work to develop accurate models to predict the future impact of global earth warming, researchers, policy makers, and industry leaders are coming to terms with what can be done today to halt and reverse the human contributions to global climate change impact.

In the “business as usual” emissions scenario, climate change will have an array of substantial impacts on our society and the environment by the end of this century. Patterns of rainfall and drought are projected to shift in such a way that some regions currently stressed for water resources, such as the desert southwest of the United States and the Middle East, are likely to become drier. More intense rainfall events in other regions, such as Europe and the mid-western United States, could lead to increased flooding. Heat waves like the one in Europe in summer 2003, which killed more than thirty thousand people, are projected to become far more common. Atlantic hurricanes are likely to reach greater intensities, potentially doing far more damage to coastal infrastructure.

Furthermore, regions such as the Arctic are expected to warm faster than the rest of the globe. Disappearing Arctic sea ice already threatens wildlife, including polar bears and walruses. Given another 2°C warming (3.6°F), a substantial portion of the Greenland ice sheet is likely to melt. This event, combined with other factors, could lead to more than 1 meter (about 3 feet) of sea-level rise by the end of the century. Such a rise in sea level would threaten many American East Coast and Gulf Coast cities, as well as low-lying coastal regions and islands around the world. Food production in tropical regions, already insufficient to meet the needs of some populations, will probably decrease with future greenhouse global warming. Thee incidence of infectious disease is expected to increase in higher elevations and in latitudes with long term warming temperatures. In short, the impacts of future climate change are likely to have a devastating impact on society and our environment in the absence of intervention.

A combination of legislation and technology has helped clean up many of the world’s coal-burning plants. Both developed and developing countries have adopted increasingly stringent environmental regulations to govern emissions from coal-fired power plants. In the United States, all coal-fired power plants built after 1978 must be equipped with postcombustion cleanup devices to capture pollutants before they escape into the atmosphere. Cyclones, baghouses, and electrostatic precipitators filter out nearly 99% of the particulates. Flue gas scrubbers use a slurry of crushed limestone and water to absorb sulfur oxides from flue gas. The limestone reacts with the sulfur dioxide to form calcium sulfate, which may be used to produce wallboard. Staged combustion and low-NOx burners are used to burn coal to minimize NOx formation. Another strategy, selective catalytic reduction, reacts ammonia with NOx over a catalyst to produce nonpolluting nitrogen and water vapor.

Conventional coal-fired power plants capture pollutants from the flue gas after it leaves the boiler. Circulating fluidized bed (CFB) combustors capture most of the pollutants before they leave the furnace. Crushed coal particles and limestone circulate inside the CFB combustor, suspended by an upward flow of hot air. Sulfur oxides released during combustion are absorbed by the limestone, forming calcium sulfate, which drops to the bottom of the boiler. The CFB combustor operates at a lower temperature (14001F) compared to pulverized coal (PC) boilers (27001F), which also helps reduce the formation of NO x .

Precombustion coal cleaning is another strategy to reduce sulfur emissions by cleaning the coal before it arrives at the power plant. Sulfur in coal is present as pyrite (FeS2 ), which is physically bound to the coal as tiny mineral inclusions, and as ‘‘organic sulfur,’’ which is chemically bound to the carbon and other atoms in coal. Pyrite is removed in a coal preparation plant, where coal is crushed into particles less than 2 inches in size and is washed in a variety of devices that perform gravity-based separations. Clean coal floats to the surface, whereas pyrite and other mineral impurities sink. Additional cleaning may be performed with flotation cells, which separate coal dust from its impurities based on differences in surface properties. Precombustion removal of organic sulfur can be accomplished only by chemical cleaning. So far, coal combustion emissions and chemical cleaning has proved to be too costly, thus flue gas scrubbers are often required to achieve near-complete removal of sulfur pollutants.

The tightening of environmental regulations is likely to continue throughout the world. In the United States, for example, by December 2008, it is anticipated that coal-fired power plants will have to comply with maximum emission levels for mercury. Emissions of mercury and other trace metals, such as selenium, are under increasing scrutiny of coal combustion emissions because of suspected adverse effects on public health.

Coal is sometimes combusted with waste material as a combined waste reduction/electricity production strategy. The disposal of waste from agriculture and forestry (biomass), municipalities, and hospitals becomes costly when landfill space is limited. Some wastes, particularly biomass feedstock, are combustible, but their low energy density (compared with coal) limits their use as an electricity production fuel. Blending coal with these fuels provides an economical method to produce electric power, reduce waste, and decrease coal plant emissions. Most wood wastes, compared to coal, contain less fuel nitrogen and burn at lower temperatures. These characteristics lead to lower NO x formation. In addition, wood contains minimal sulfur ( o 0.1% by weight) and thus reduces the load on scrubbers and decreases scrubber waste biomass.

Numerous electric utilities have demonstrated that 1–8% of woody drying biomass can be blended with coal with no operational problems. Higher blends may also be used, but require burner and feed intake modifications as well as a separate feed system for the waste fuel. Cofiring in fluidized bed boilers may avoid some of these drawbacks, but the economics of co-firing are not yet sufficiently attractive to make it a widespread practice.

The moisture content of the feedstock affects the gas composition and the energy balance of the process since gasification is an endothermic process. Water vapor, however, is an essential component of gasification reactions. Therefore, there is a trade-off between the extent of fuel drying and the quality of product gas. Drying of the feedstock to a moisture content of approximately 15% is commonly adopted. Fuel drying is likely to be the most energy intensive activity in the biomass gasification process. Important contributions can be made to the energy balance by using flue gases or steam to dry the biomass. The heat used for drying does not have to be high temperature, and a low temperature level is actually desired because it will prevent the evaporation of undesirable organic components. (more…)

Transport applications tend to demand rapid start-up and instant dynamic response from fuel cell systems, so a high-temperature fuel cell is unlikely to be competitive as the main engine in applications such as cars and buses. The prime candidate for these vehicle propulsion systems is the Polymer Electrolyte Fuel Cells, which exhibits both of the above characteristics while also having very high power density. This is important as it must also occupy a similar amount of space to an internal combustion engine. Of recent interest has been the development of auxiliary power units for vehicles, in which the fuel cell meets the onboard electric load of the vehicle. Both Polymer Electrolyte Fuel Cells and ITSOFCs are under development for this application. (more…)

Polymer Electrolyte Fuel Cells have high-power density, rapid startup, and low-temperature operation (around 80 to 120 C), and so are ideal for use in applications such as energy transport and battery replacement. The electrolyte used is a proton conducting polymer. This is typically a perfluorinated polymer, though other hydrocarbon-based membranes are under development in an attempt to reduce cost or to enable operation at temperatures approaching 200 C. The catalytically active layer sits adjacent to the membrane, supported on a PTFE treated carbon paper, which acts as current collector and gas diffusion layer. For operation on pure hydrogen, platinum is the most active catalyst, but alloys of platinum and ruthenium are used when higher levels of carbon monoxide are present (CO is a poison in all low temperature fuel cells). (more…)