Air-blown circulating fluidized bed gasifiers are of interest because they produce a good quality, low calorific value (LCV) gas (4–6 MJ/Nm 3 ) and possess a very high carbon conversion efficiency while allowing high capacity, good tolerance to variations in fuel quality, and reliable operation. The high and homogeneously distributed temperatures and the use of particular bed materials, such as dolomite, favor tar cracking. Successful tar cracking can also be achieved using secondary circulating fluidized bed reactors. Also, successful tests on catalytic tar cracking have been performed, for example, by introducing nickel compounds into the gasifier. Sulfur control is made easier because of the significant reduction that can be achieved by adding limestone or dolomite to the gasifier bed. (more…)

A combination of legislation and technology has helped clean up many of the world’s coal-burning plants. Both developed and developing countries have adopted increasingly stringent environmental regulations to govern emissions from coal-fired power plants. In the United States, all coal-fired power plants built after 1978 must be equipped with postcombustion cleanup devices to capture pollutants before they escape into the atmosphere. Cyclones, baghouses, and electrostatic precipitators filter out nearly 99% of the particulates. Flue gas scrubbers use a slurry of crushed limestone and water to absorb sulfur oxides from flue gas. The limestone reacts with the sulfur dioxide to form calcium sulfate, which may be used to produce wallboard. Staged combustion and low-NOx burners are used to burn coal to minimize NOx formation. Another strategy, selective catalytic reduction, reacts ammonia with NOx over a catalyst to produce nonpolluting nitrogen and water vapor.

Conventional coal-fired power plants capture pollutants from the flue gas after it leaves the boiler. Circulating fluidized bed (CFB) combustors capture most of the pollutants before they leave the furnace. Crushed coal particles and limestone circulate inside the CFB combustor, suspended by an upward flow of hot air. Sulfur oxides released during combustion are absorbed by the limestone, forming calcium sulfate, which drops to the bottom of the boiler. The CFB combustor operates at a lower temperature (14001F) compared to pulverized coal (PC) boilers (27001F), which also helps reduce the formation of NO x .

Precombustion coal cleaning is another strategy to reduce sulfur emissions by cleaning the coal before it arrives at the power plant. Sulfur in coal is present as pyrite (FeS2 ), which is physically bound to the coal as tiny mineral inclusions, and as ‘‘organic sulfur,’’ which is chemically bound to the carbon and other atoms in coal. Pyrite is removed in a coal preparation plant, where coal is crushed into particles less than 2 inches in size and is washed in a variety of devices that perform gravity-based separations. Clean coal floats to the surface, whereas pyrite and other mineral impurities sink. Additional cleaning may be performed with flotation cells, which separate coal dust from its impurities based on differences in surface properties. Precombustion removal of organic sulfur can be accomplished only by chemical cleaning. So far, coal combustion emissions and chemical cleaning has proved to be too costly, thus flue gas scrubbers are often required to achieve near-complete removal of sulfur pollutants.

The tightening of environmental regulations is likely to continue throughout the world. In the United States, for example, by December 2008, it is anticipated that coal-fired power plants will have to comply with maximum emission levels for mercury. Emissions of mercury and other trace metals, such as selenium, are under increasing scrutiny of coal combustion emissions because of suspected adverse effects on public health.

Coal is sometimes combusted with waste material as a combined waste reduction/electricity production strategy. The disposal of waste from agriculture and forestry (biomass), municipalities, and hospitals becomes costly when landfill space is limited. Some wastes, particularly biomass feedstock, are combustible, but their low energy density (compared with coal) limits their use as an electricity production fuel. Blending coal with these fuels provides an economical method to produce electric power, reduce waste, and decrease coal plant emissions. Most wood wastes, compared to coal, contain less fuel nitrogen and burn at lower temperatures. These characteristics lead to lower NO x formation. In addition, wood contains minimal sulfur ( o 0.1% by weight) and thus reduces the load on scrubbers and decreases scrubber waste biomass.

Numerous electric utilities have demonstrated that 1–8% of woody drying biomass can be blended with coal with no operational problems. Higher blends may also be used, but require burner and feed intake modifications as well as a separate feed system for the waste fuel. Cofiring in fluidized bed boilers may avoid some of these drawbacks, but the economics of co-firing are not yet sufficiently attractive to make it a widespread practice.