Photoelectrolysis Using Metal Oxides And Other Semiconductors

Photoelectrolysis
Certain materials, generally metal oxides, can sustain the unassisted photo-electrolysis of water into H2 and O2. The energy contained in the photons that are absorbed by these materials can in many cases be efficiently converted into energy stored into the chemical fuels produced by the photo-electrolysis system. However, these materials have optical absorption thresholds (band gaps) that are too large to permit effective absorption of the visible and infrared portions of the solar spectrum, thereby wasting a large fraction of the incident solar energy and yielding overall energy conversion efficiencies of o 1%. Modification of metal oxide materials has been claimed to be much more promising, with a modified TiO 2 photo-anode yielding 8% efficiency in the photo-assisted splitting of water into H2 and O2 . (more…)

Artificial Photosynthetic Devices

Several molecular systems have been constructed that mimic various aspects of photosynthesis. Two of these utilize molecular systems that are derived from natural photosynthesis but that incorporate chemically based modifications to produce artificial photosynthetic devices. These devices use artificial photosynthetic pigments to drive chemical reactions across lipid bilayers or use noble metal catalysts to change the function of the photosynthetic process to produce hydrogen and oxygen instead of sugars ethanol and oxygen. Neither of these systems are sufficiently robust to be operated for extended periods of time as energy unit conversion devices, but they have shown that it is possible to produce artificial photosynthetic assemblies that function well in a laboratory setting. (more…)

The Future of Solar Energy Through Photosynthesis

solar energy photosynthesis
In the mid-1880s, Charles Fritts built the first solar cell formed by selenium coated with a thin layer of gold and with an energy efficiency of 1%. However, it was not until 1954 that Bell Labs discovered accidentally that would be the first commercial solar cell, with silicon as the base. (more…)